Nylon 12 fine particulates

They are spherical nylon fine powders developed by Toray. They provide not only the specific properties of polyamide such as heat resistance and chemical resistance, but also have a uniform particle size, smooth surface, and excellent dispersiveness, exhibiting a smooth sliding property and unique flexibility.

Features

Features of Nylon 12 fine particulates

Spherical shape

Uniform size and shape from all directions stabilize product quality.

Smooth particle surface

The smooth particle surface minimizes friction and contributes to good spreadability and smoothness.

Sharp particle size distribution

Because the particle size is uniform, product quality is stabilized. Since it does not contain coarse particles, it also contributes to good dispersiveness.

Dispersiveness

With excellent dispersiveness, a uniform finish can be obtained in cosmetics and paints.

Two particle lineups

There are two lineups: SP500 with an average particle size of 5 µm and SP10 with 10 µm.

Reasons to Choose

Spherical particles with sufficient spreadability and smoothness

We realized the production of spherical particles through our proprietary polymer design technology. The particle surface is also smooth, and it has a very regular particle shape. Having a smooth spherical shape minimizes friction and contributes to good spreadability and smoothness. Due to these features, it has proven track record as a sensory improver in the cosmetics field spanning many years.

SEM image of PA12

粒子拡大図
粒子拡大図

Sharp particle size distribution (uniform particle size) contributing to dispersiveness and quality stability

It exhibits a very sharp particle size distribution and has a uniform particle size. For this reason, it has excellent dispersiveness and stabilizes product quality, making it suitable for cosmetic applications, anti-blocking agents for films, semiconductor encapsulants, and adhesives. We offer two grades with average particle sizes of approximately 5 µm (SP500) and 10 µm (SP10).

Particle size distribution of Nylon 12 fine particulates SP500

Particle size distribution of Nylon 12 fine particulates SP10

Property values of SP500 and SP10

Item SP500 SP10
Average particle size 5~6µm 7~10µm
Specific gravity 1.02 1.02
Melting point 165°C~171°C 165°C~171°C
Bulk density 4.5ml/g 3.2ml/g
Water-soluble content 0.5% or less 0.4% or less
Ignition residue 0.5% or less 0.5% or less
Aqueous suspension pH 6.0~8.0 6.0~8.0
Arsenic 1 ppm or less as AB203 1 ppm or less as AB203
Heavy metals 10 ppm or less 10 ppm or less
Refractive index 1.53 -
Modulus 1.12GPa -
10% Compressive displacement strength 40MPa -
Dielectric loss tangent 0.0082 -
Dielectric constant 2.293 -

*This data represents typical measured values obtained under specific conditions and is not a guaranteed value.

Applications

Cosmetics

Nylon 12 fine particulates (PA12) have a history of over 50 years as sensory improvers in cosmetics. Among the particles used as sensory improvers, they are evaluated as being particularly excellent in providing a "moist feel" and "softness" to the final products, and are widely used in applications such as foundation, color cosmetics, sunscreen, hair spray, and creams.

Positioning of cosmetic powders

Source: Created by Toray based on "Current Status and Future Prospects of the Fine Powder Market 2023" by Fuji Chimera Research Institute, Inc.

In 2024, we developed Nylon 4 fine particulates (PA4) with marine biodegradability as an alternative to microplastic beads for cosmetics, which are increasingly regulated in Europe. While this product exhibits the same sphericity and particle size distribution as Nylon 12 fine particulates (SP500), it has been confirmed to show sufficient biodegradability by the OECD 301F* test.

*OECD 301F: A type of biodegradability test specified in the OECD test guidelines. If 60% or more biodegradability is confirmed in 28 days, it is determined to be "readily biodegradable."

PA4 (development product) SEM image

PA4 (development product)  particle size distribution

PA4 (development product) confirmation of biodegradability

Biodegradability (OECD 301F)

In activated sludge, if it is decomposed by 60% or more in 28 days (N2), it is recognized as "readily biodegradable."

→PA4 (development product) confirmed high biodegradability of about 90% in 28 days.

Marine biodegradability (ASTM D6691)

Confirmation of biodegradability in the ocean, which has fewer microorganisms than activated sludge.

→PA4 (development product) confirmed biodegradability exceeding 90% in 120 days.

Industrial products

Leveraging the characteristics of the particle shape, which is spherical and has a uniform particle size, as well as the heat resistance, chemical resistance, and softness that are characteristics of polyamide, its adoption in industrial applications is also expanding. Main application examples include the following.

  • Anti-blocking agent for films
  • Semiconductor encapsulants and adhesives
  • Inks and paints
  • OA rubber rolls

Image of PA12 utilization as an anti-blocking agent for films
ナイロン12微粒子:アンチブロッキング効果/別の役割効果を持つフィルムがくっつかないように浮かせることで、各フィルムの効果を十分に発揮することができる。

Image of PA12 utilization in sealing/adhesion including conductive adhesives

SPの添加によって、粘度や体積抵抗、基盤⇔ICチップの密着性が良化。また、剥離強度UPの効果も確認されれた銀の添加量を減らせるメリットもあり。応力緩和剤として、接着剤関係だけでなく、封止関係全体への展開が期待される。

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